Nonstandard
electroconvection
In nematics with ea < 0 and sa < 0 or with ea > 0 and sa > 0 the Carr-Helfrich
mechanism cannot provide a positive feedback, thus the standard model of EC
excludes the occurrence of EC.
Experimentally,
however, EC patterns could be observed even in such compounds. Those
instabilities have therefore been coined nonstandard EC.
Nematics
with ea
< 0 and sa
< 0:
Parallel
rolls and oblique rolls with large obliqueness have been observed in planar
samples depending on the frequency. It
has been proved recently that extension of the standard model of EC by
including flexoelectricity can explain this pattern formation (the charge
separation is due to the flexoelectric polarization instead of sa). |
Oblique rolls Parallel rolls |
Nematics
with ea
> 0 and sa
> 0:
A
direct transition to cellular patterns has been observed in homeotropic 5CB
followed by another transition at higher voltages to a roll pattern. The
same patterns are observable also in planar samples; however, they are
preceded by a Freedericksz transition. A
precise theoretical explanation of this pattern formation is still in demand. |
Cellular pattern Roll pattern |
Prewavy pattern:
The
prewavy pattern is a large wavelength stripe pattern
characterized with azimuthal director modulation and
the stripes running normal to the director. It has been observed as a high
frequency pattern in calamitic nematics with ea < 0 and sa > 0 as well as in bent-core nematics with ea < 0
and sa < 0.
Its occurrence cannot be explained within the standard model of EC.
Prewavy pattern in MBBA |
Prewavy2 and Prewavy1 patterns in a bent-core compound |